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    宋成立, 宋晓俊, 陈庆国, 李坤, 贾海东, 李广山. 20钢在油气田中CO2与H2S共存环境下的腐蚀行为及机理[J]. 机械工程材料, 2023, 47(3): 60-65. DOI: DOI: 10.11973/jxgccl202303011
    引用本文: 宋成立, 宋晓俊, 陈庆国, 李坤, 贾海东, 李广山. 20钢在油气田中CO2与H2S共存环境下的腐蚀行为及机理[J]. 机械工程材料, 2023, 47(3): 60-65. DOI: DOI: 10.11973/jxgccl202303011
    SONG Chengli, SONG Xiaojun, CHEN Qingguo, LI Kun, JIA Haidong, LI Guangshan. Corrosion Behavior and Mechanism of 20 Steel under CO2/H2S Coexisted Environment in Oil and Gas Field[J]. Materials and Mechanical Engineering, 2023, 47(3): 60-65. DOI: DOI: 10.11973/jxgccl202303011
    Citation: SONG Chengli, SONG Xiaojun, CHEN Qingguo, LI Kun, JIA Haidong, LI Guangshan. Corrosion Behavior and Mechanism of 20 Steel under CO2/H2S Coexisted Environment in Oil and Gas Field[J]. Materials and Mechanical Engineering, 2023, 47(3): 60-65. DOI: DOI: 10.11973/jxgccl202303011

    20钢在油气田中CO2与H2S共存环境下的腐蚀行为及机理

    Corrosion Behavior and Mechanism of 20 Steel under CO2/H2S Coexisted Environment in Oil and Gas Field

    • 摘要: 利用高温高压动态反应釜模拟油气田CO2和H2S共存环境的实际工况,通过腐蚀试验分析了20钢在不同CO2分压(0.01,0.05,0.21,0.50 MPa)和H2S分压(0.000 3,0.003,0.01,0.05 MPa)下的腐蚀行为以及CO2和H2S分压对均匀腐蚀和点蚀的影响程度。结果表明:在H2S分压为0.003 MPa条件下,当CO2分压为0.01,0.05 MPa时,20钢主要发生均匀腐蚀,随着CO2分压的继续增大,点蚀越来越严重;在CO2分压为0.05 MPa条件下,当H2S分压为0.000 3 MPa时,20钢表面腐蚀轻微,随着H2S分压的增大,腐蚀加剧,但仍主要发生均匀腐蚀;H2S和CO2分压对20钢的均匀腐蚀速率和点蚀速率均具有十分显著的影响,H2S分压对均匀腐蚀的影响程度较大,而CO2分压对点蚀的影响程度较大。

       

      Abstract: The high temperature and high pressure dynamic reactor was used to simulate the actual working conditions of CO2 and H2S coexisted environment in oil and gas field. The corrosion behavior of 20 steel at different CO2 partial pressures (0.01, 0.05, 0.21, 0.50 MPa) and H2S partial pressures (0.000 3, 0.003, 0.01, 0.05 MPa) and the degree of influence of CO2 and H2S partial pressure on uniform corrosion and pitting were studied by corrosion tests. The results show that under H2S partial pressure of 0.003 MPa, when CO2 partial pressure was 0.01, 0.05 MPa, uniform corrosion of 20 steel mainly occurred; with increasing CO2 partial pressure, pitting became serious. Under CO2 partial pressure of 0.05 MPa, when H2S partial pressure was 0.000 3 MPa, 20 steel's surface corrosion was slight; with increasing H2S partial pressure, the corrosion was intensified, but still uniform corrosion mainly occurred. H2S and CO2 partial pressure had a very significant impact on 20 steel's uniform corrosion rate and pitting rate; H2S partial pressure had a relatively great effect on uniform corrosion, and CO2 partial pressure had a relatively great effect on pitting.

       

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